Acceptor Energy Offset Manages Ultrafast Recombination Dynamics in Donor-Acceptor Mixtures
نویسندگان
چکیده
منابع مشابه
Ultrafast Energy Transfer in Ultrathin Organic Donor/Acceptor Blend
It is common knowledge that poly(3-hexylthiophene) (P3HT)/[6,6]-phenyl-C61-butyric acid methyl ester (PCBM) blend, a prototype system for bulk heterojunction (BHJ) solar cells, consists of a network of tens of nanometers-large donor-rich and acceptor-rich phases separated by extended finely intermixed border regions where PCBM diffuse into P3HT. Here we specifically address the photo-induced dy...
متن کاملSolvent and spectral effects in the ultrafast charge recombination dynamics of excited donor-acceptor complexes.
The charge recombination dynamics of excited donor-acceptor complexes consisting of hexamethylbenzene (HMB), pentamethylbenzene (PMB), and isodurene (IDU) as electron donors and tetracyanoethylene (TCNE) as electron acceptor in various polar solvents has been investigated within the framework of the stochastic approach. The model accounts for the reorganization of intramolecular high-frequency ...
متن کاملUltrafast Photoinduced Electron Transfer in Spiro-type Donor- Acceptor Systems
Perpendicular orientation of the electron donor in relation to the acceptor in the ground state seems to contribute significantly to high rate constants of the photoinduced intramolecular electron transfer (PET) in electron donor-acceptor (DA) type molecules [1]. A very interesting class of molecules in this respect are systems build around a spiro-type carbon atom, separating mutually orthogon...
متن کاملUltrafast photoinduced charge transport in Pt(II) donor-acceptor assembly bearing naphthalimide electron acceptor and phenothiazine electron donor.
Visible light-induced charge transfer dynamics were investigated in a novel transition metal triad acceptor-chromophore-donor, (NDI-phen)Pt(II)(-C≡C-Ph-CH2-PTZ)2 (1), designed for photoinduced charge separation using a combination of time-resolved infrared (TRIR) and femtosecond electronic transient absorption (TA) spectroscopy. In 1, the electron acceptor is 1,4,5,8-naphthalene diimide (NDI), ...
متن کاملEffect of the excitation wavelength on the ultrafast charge recombination dynamics of donor-acceptor complexes in polar solvents.
The effect of the excitation wavelength on the charge recombination (CR) dynamics of several donor-acceptor complexes (DACs) composed of benzene derivatives as donors and of tetracyanoethylene or pyromellitic dianhydride as acceptors has been investigated in polar solvents using ultrafast time-resolved spectroscopy. Three different wavelength effects have been observed. (1) With complexes exhib...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: EPJ Web of Conferences
سال: 2013
ISSN: 2100-014X
DOI: 10.1051/epjconf/20134105036